명예교수

박재욱교수

  • Ph.D., '87, Princeton Univ.
  • Organic Chemistry, Organometallic Chemistry
  • pjw@postech.ac.kr
학력 및 주요경력

1980-서울대학교(학사)

1982-서울대학교(석사)

1987-Princeton University(박사)

전문분야

유기화학

국제전문학술지

Generation of N-H Imines from α-Azidocarboxylic Acids through Ru-Catalyzed Decarboxylation,Journal of Organic Chemistry,86,17409~1741(2021)

Asymmetric Synthesis of Biaryl Diols via Dynamic Kinetic Resolution,Bulletin of the Korean Chemical Society,42,1028~1032(2021)

Concurrent Formation of N-H Imines and Carbonyl Compounds by Ruthenium-Catalyzed C-C Bond Cleavage of beta-Hydroxy Azides,ORGANIC LETTERS,22,4608~4613(2020)

Base-Free Dynamic Kinetic Resolution of Secondary Alcohols with a Ruthenium-Lipase Couple,JOURNAL OF ORGANIC CHEMISTRY,84,16293~1629(2019)

Ionic-surfactant-coated subtilisin: activity, enantioselectivity, and application to dynamic kinetic resolution of secondary alcohols,ORGANIC & BIOMOLECULAR CHEMISTRY,15,8836~8844(2017)

Ruthenium Bisammine Complex and Its Reaction with Aryl Azides,ORGANOMETALLICS,36,3471~3476(2017)

Chemoselective, Isomerization-Free Synthesis of N-Acylketimines from N?H Imines,ADVANCED SYNTHESIS & CATALYSIS,359,1503~1507(2017)

Zinc-Mediated syn-Selective Crotylation of N-Unsubstituted Imines,Asian Journal of Organic Chemistry,6,441~444(2017)

Redox reaction between benzyl azides and aryl azides: concerted synthesis of aryl nitriles and anilines,ORGANIC & BIOMOLECULAR CHEMISTRY,7,1636~1641(2017)

Catalytic transformation of esters of 1,2-azido alcohols into a-amido ketones,CHEMICAL COMMUNICATIONS,52,6549~6552(2016)

Synthesis of 1H-azadienes and application to one-pot organic transformations,RSC ADVANCES,6,661~668(2016)

Synthesis of Enamides by Ruthenium-Catalyzed Reaction of Alkyl Azides with Acid Anhydrides in Ionic Liquid,CHEMCATCHEM,7,4030~4034(2015)

Highly enantioselective dynamic kinetic resolution of alkyl aryl carbinols carrying a trimethylsilyl group with a highly active lipoprotein lipase preparation,TETRAHEDRON-ASYMMETRY,26,840~845(2015)

A Stereoselective Access to Cyclic cis-1,2-Amino Alcohols from trans-1,2-Azido Alcohol Precursors,Advanced Synthesis & Catalysis,357,1398~1404(2015)

Fast and Complete Transimination of N-H Imines into O-Alkyl Oximes,Asian Journal of Organic Chemistry,4,316~319(2015)

Dynamic Kinetic Resolution of Diarylmethanols with an Activated Lipoprotein Lipase,ACS CATALYSIS,5,683~689(2015)

Stereoselective Synthesis of Highly Substituted α-Silylamines from Silylmethyl Azides under Ru Catalysis,European Journal of Organic Chemistry,2014,7577~7581(2014)

Synthesis of Piperidones from Benzyl Azides and Acetone,Bulletin of the Korean Chemical Society,35,3433~3436(2014)

Exploiting the Nucleophilicity of N-H Imines: Synthesis of Enamides from Alkyl Azides and Acid Anhydrides,Advanced Synthesis & Catalysis,356,2769~2774(2014)

C–H Activation Guided by Aromatic N–H Ketimines: Synthesis of Functionalized Isoquinolines Using Benzyl Azides and Alkynes,The Journal of Organic Chemistry,79,9094~9103(2014)

A Ru-catalyzed one-pot synthesis of homopropargylic amines from alkyl azides under photolytic conditions,RSC Advances,4,20632~2063(2014)

Highly Chemoselective Aerobic Oxidation of Amino Alcohols into Amino Carbonyl Compounds,Angewandte Chemie International Edition,53,3236~3240(2014)

Novel Catalyst System for Hydrostannation of Alkynes,CHEMISTRY-A EUROPEAN JOURNAL,20,1267~1271(2014)

Highly enantioselective enzymatic resolution of aromatic beta-amino acid amides with Pd-catalyzed racemization,TETRAHEDRON-ASYMMETRY,24,1449~1452(2013)

Postsynthetic Functionalization of a Hollow Silica Nanoreactor with Manganese Oxide-Immobilized Metal Nanocrystals Inside the Cavity,JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,135,15714~1571(2013)

Candida antarctica lipase A and Pseudomonas stutzeri lipase as a pair of stereocomplementary enzymes for the resolution of 1,2-diarylethanols and 1,2-diarylethanamines,TETRAHEDRON LETTERS,54,1185~1188(2013)

Kinetic and Dynamic Kinetic Resolution of Secondary Alcohols with Ionic-Surfactant-Coated Burkholderia cepacia Lipase: Substrate Scope and Enantioselectivity,JOURNAL OF ORGANIC CHEMISTRY,78,2571~2578(2013)

Can Adenosine Triarsenate Role as an Energy Carrier?,BULLETIN OF THE KOREAN CHEMICAL SOCIETY,34,361~362(2013)

A Magnetically Separable Gold Catalyst for Chemoselective Reduction of Nitro Compounds,ORGANIC & BIOMOLECULAR CHEMISTRY,11,395~399(2013)

Characterization and Utility of N-Unsubstituted Imines Synthesized from Alkyl Azides by Ruthenium Catalysis,ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,51,10851~1085(2012)

Catalytic Synthesis of Silanols from Hydrosilanes and Applications,ACS CATALYSIS,2,1539~1549(2012)

Transformation of Silanes into Silanols using Water and Recyclable Metal Nanoparticle Catalysts,CHEMCATCHEM,4,521~524(2012)

Highly Efficient and Chemoselective Ruthenium-Catalyzed Hydrosilylation of Aldehydes,ADVANCED SYNTHESIS & CATALYSIS,353,3363~3366(2011)

Ionic-Surfactant-Coated Burkholderia cepacia Lipase as a Highly Active and Enantioselective Catalyst for the Dynamic Kinetic Resolution of Secondary Alcohols,ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,50,10944~1094(2011)

Recyclable Copper Catalyst for meta-Selective C-H Bond Arylation,CHEMCATCHEM,3,1127~1129(2011)

Pd-catalyzed Dehalogenation of Aromatic Halides Under Solvent-free Conditions Using Hydrogen Balloon,BULLETIN OF THE KOREAN CHEMICAL SOCIETY,32,1074~1076(2011)

[{eta(5)-Ar(4)C(4)COC(=O)Ar}Ru(CO)(2)Cl] in Racemization and DKR of Secondary Alcohols,CHEMCATCHEM,3,354~359(2011)

Dynamic Kinetic Resolution of Amines and Amino Acids by Enzyme-Metal Cocatalysis,CHEMCATCHEM,3,271~277(2011)

Fast racemization and dynamic kinetic resolution of primary benzyl amines,TETRAHEDRON LETTERS,51,5581~5584(2010)

Silylation of primary alcohols with recyclable ruthenium catalyst and hydrosilanes,TETRAHEDRON LETTERS,51,4573~4575(2010)

Highly efficient solvent-free catalytic hydrogenation of solid alkenes and nitro-aromatics using Pd nanoparticles entrapped in aluminum oxy-hydroxide,TETRAHEDRON LETTERS,51,4250~4252(2010)

Photoactivated Racemization Catalyst for Dynamic Kinetic Resolution of Secondary Alcohols,JOURNAL OF ORGANIC CHEMISTRY,75,5740~5742(2010)

Chemoenzymatic synthesis of the calcimimetics (+)-NPS R-568 via asymmetric reductive acylation of ketoxime intermediate,TETRAHEDRON LETTERS,51,3536~3537(2010)

Chemoenzymatic Synthesis of Rivastigmine via Dynamic Kinetic Resolution as a Key Step,JOURNAL OF ORGANIC CHEMISTRY,75,3105~3108(2010)

Chemoenzymatic Dynamic Kinetic Resolution of Alcohols and Amines,EUROPEAN JOURNAL OF ORGANIC CHEMISTRY,0,999~1015(2010)

Synthesis of Optically Active Amino Acid Derivatives via Dynamic Kinetic Resolution,JOURNAL OF ORGANIC CHEMISTRY,74,9543~9545(2009)

"Synthesis of 2,5-Diaminoquinones by One-Pot Copper-Catalyzed Aerobic Oxidation of Hydroquinones and Addition Reaction of Amines",ADVANCED SYNTHESIS & CATALYSIS,351,2573~2578(2009)

Formation of an Iodide-Bridged Diruthenium Complex from [(n(5)- Ph4C4COH)(CO)(2)RuI] and [(Ph4C4CO)(CO)(2)Ru](2): An Efficient Catalyst for Alcohol Oxidation with Ag2O,ORGANOMETALLICS,28,4624~4627(2009)

Ruthenium-Catalyzed, One-Pot Alcohol Oxidation-Wittig Reaction Producing alpha,beta-Unsaturated Esters",EUROPEAN JOURNAL OF ORGANIC CHEMISTRY,0,2943~2946(2009)

ONE-POT SYNTHESIS OF IMINES AND SECONDARY AMINES BY PD-CATALYZED COUPLING OF BENZYL ALCOHOLS AND PRIMARY AMINES,JOURNAL OF ORGANIC CHEMISTRY,74,2877~2879(2009)

Recyclable gold nanoparticle catalyst for the aerobic alcohol oxidation and C-C bond forming reaction between primary alcohols and ketones under ambient conditions,TETRAHEDRON,65,0000001461(2009)

Asymmetric reductive acylation of aromatic ketoximes by enzyme-metal cocatalysis,JOURNAL OF ORGANIC CHEMISTRY,73,0000004302(2008)

I&EC 117-Solvent-free hydrogenation of solid olefins and nitroaromatics by palladium nanoparticles embedded in alumina hydroxide,ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY,235,117-IEC(2008)

Highly enantioselective dynamic kinetic resolution of 1,2-diarylethanols by a lipase-ruthenium couple,ORGANIC LETTERS,10,0000001295(2008)

Racemization catalysts for the dynamic kinetic resolution of alcohols and amines,COORDINATION CHEMISTRY REVIEWS,252,0000000647(2008)

Heterogeneous copper catalyst for the cycloaddition of azides and alkynes without additives under ambient conditions,ORGANIC LETTERS,10,497~500(2008)

(S)-selective dynamic kinetic resolution of allylic alcohols by enzyme-metal bicatalysis,BULLETIN OF THE KOREAN CHEMICAL SOCIETY,28,2096~2098(2007)

Rhodium and iridium nanoparticles entrapped in aluminum oxyhydroxide nanofibers: Catalysts for hydrogenations of arenes and ketones at room temperature with hydrogen balloon,ADVANCED SYNTHESIS & CATALYSIS,349,2039~2047(2007)

Magnetically separable Pd catalyst for highly selective epoxide hydrogenolysis under mild conditions,ORGANIC LETTERS,9,3417~3419(2007)

Air-stable racemization catalysts for the dynamic kinetic resolution of secondary alcohols,JOURNAL OF ORGANIC CHEMISTRY,72,6860~6864(2007)

Dynamic kinetic resolution of primary amines with a recyclable Pd nanocatalyst for racemization,ORGANIC LETTERS,9,1157~1159(2007)

Palladium nanoparticles in polymers: Catalyst for alkene hydrogenation, carbon-carbon cross-coupling reactions, and aerobic alcohol oxidation,SYNTHESIS-STUTTGART,0,3790~3794(2006)

Acceptor-free alcohol dehydrogenation by recyclable ruthenium catalyst,ORGANIC LETTERS,8,2543~2545(2006)

Effect of the anchoring group in Ru-bipyridyl sensitizers on the photoelectrochemical behavior of dye-sensitized TiO2 electrodes: Carboxylate versus phosphonate linkages,JOURNAL OF PHYSICAL CHEMISTRY B,110,8740~8749(2006)

Air-stable racemization catalyst for dynamic kinetic resolution of secondary alcohols at room temperature,ORGANIC LETTERS,7,4523~4526(2005)

Dynamic kinetic resolutions and asymmetric transformations by enzyme-metal combo catalysis,BULLETIN OF THE KOREAN CHEMICAL SOCIETY,26,515~522(2005)

Palladium nanoparticles entrapped in aluminum hydroxide: Dual catalyst for alkene hydrogenation and aerobic alcohol oxidation,ORGANIC LETTERS,7,1077~1079(2005)

Recyclable palladium catalyst for highly selective alpha alkylation of ketones with alcohols,ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,44,6913~6915(2005)

Rhodium nanoparticles entrapped in boehmite nanofibers: recyclable catalyst for arene hydrogenation under mild conditions,CHEMICAL COMMUNICATIONS,0,5667~5669(2005)

Molecular weight distribution of branched polystyrene: Propagation of Poisson distribution,MACROMOLECULES,37,8805~8807(2004)

Effects of surface anchoring groups (Carboxylate vs phosphonate) in ruthenium-complex-sensitized TiO2 on visible light reactivity in aqueous suspensions,JOURNAL OF PHYSICAL CHEMISTRY B,108,14093~1410(2004)

One-pot synthesis of recyclable palladium catalysts for hydrogenations and carbon-carbon coupling reactions,TETRAHEDRON LETTERS,45,7057~7059(2004)

Synthesis of aminocyclopentadienyl ruthenium chloride,INORGANIC CHEMISTRY COMMUNICATIONS,7,988~989(2004)

Alumina-supported ruthenium catalysts for the racemization of secondary alcohols,BULLETIN OF THE KOREAN CHEMICAL SOCIETY,25,931~933(2004)

Heterogeneous shvo-type ruthenium catalyst: dehydrogenation of alcohols without hydrogen acceptors,TETRAHEDRON LETTERS,45,4607~4610(2004)

Aminocyclopentadienyl ruthenium complexes as racemization catalysts for dynamic kinetic resolution of secondary alcohols at ambient temperature,JOURNAL OF ORGANIC CHEMISTRY,69,1972~1977(2004)

Dynamic kinetic resolution of secondary alcohols by enzyme-metal combinations in ionic liquid,GREEN CHEMISTRY,6,471~474(2004)

(S)-Selective dynamic kinetic resolution of secondary alcohols by the combination of subtilisin and an aminocyclopentadienylruthenium complex as the catalysts,JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,125,11494~1149(2003)

Dynamic kinetic resolutions and asymmetric transformations by enzymes coupled with metal catalysis,CURRENT OPINION IN BIOTECHNOLOGY,13,578~587(2002)

Facile synthesis of (eta(5)-Ph4C4COH)(CO)(2)RuCl and catalytic oxidation of alcohols with chloroform,ORGANOMETALLICS,21,0000005674(2002)

Asymmetric transformations of acyloxyphenyl ketones by enzyme-metal multicatalysis,JOURNAL OF ORGANIC CHEMISTRY,67,0000009481(2002)

Carbon nanotubes produced by tungsten-based catalyst using vapor phase deposition method,CHEMICAL PHYSICS LETTERS,361,0000000469(2002)

Temperature gradient interaction chromatography and matrix-assisted laser desorption/ionization time-of-flight mass spectrometry analysis of air terminated polystyryllithium,JOURNAL OF CHROMATOGRAPHY A,958,0000000183(2002)

Unexpected formation of the isopropylamine complex [2,3,4,5-Ph-4(eta(4)-C4CO)](CO)(2)Ru(H2NCHMe2) in the attempted synthesis of an isopropyl alcohol complex,ORGANOMETALLICS,21,0000001955(2002)

Aminocyclopentadienyl ruthenium chloride: Catalytic racemization and dynamic kinetic resolution of alcohols at ambient temperature,ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,41,2373~2376(2002)

ortho-silylation of 2,2 '-bis(oxazolinyl)-1,1 '-bis(diphenylphosphino)ferrocenes and remarkable effect of the silyl groups on the enantio selectivity in Pd-catalyzed asymmetric allylic alkylation,JOURNAL OF ORGANOMETALLIC CHEMISTRY,637,0000000099(2001)

X-ray structure and reactivity of (eta(4)-tetraphenyleyclopentadienone)(CO)(2)Ru(HOCHMe2): Unexpected stability of the neutral 2-propanol-ruthenium(0) complex with respect to beta-hydride elimination,ORGANOMETALLICS,20,0000003370(2001)

Lipase/ruthenium-catalyzed dynamic kinetic resolution of hydroxy acids, diols, and hydroxy aldehydes protected with a bulky group,JOURNAL OF ORGANIC CHEMISTRY,66,0000004736(2001)

Reactions of (eta(5)-indenyl)Ru(PPh3)(2)Cl with CH2Cl2 and CHCl3: Formation of (eta(5)-indenyl)Ru{CH2PPh2(C6H4)}(PBh(3)) and (eta(5)-indenyl) Ru(PPh3)(CO)Cl,ORGANOMETALLICS,20,0000001892(2001)

Practical ruthenium/lipase-catalyzed asymmetric transformations of ketones and enol acetates to chiral acetates,ORGANIC LETTERS,2,0000002487(2000)

Dynamic kinetic resolution of allylic alcohols mediated by ruthenium- and lipase-based catalysts,ORGANIC LETTERS,2,0000002377(2000)

Concerted catalytic reactions for conversion of ketones or enol acetates to chiral acetates,ORGANIC LETTERS,2,0000000409(2000)

Synthesis of 6,13-bis(thymidinyl)-5,12-dioxocyclams and the molecular structure of the (R,S)-isomer,BULLETIN OF THE KOREAN CHEMICAL SOCIETY,20,0000000917(1999)

Enzymatic resolution of secondary alcohols coupled with ruthenium-catalyzed racemization without hydrogen mediator,TETRAHEDRON LETTERS,40,0000006281(1999)

Synthesis of chiral 1 '-substituted oxazolinylferrocenes as chiral ligands for Pd-catalyzed allylic substitution reactions,JOURNAL OF ORGANOMETALLIC CHEMISTRY,584,0000000140(1999)

Efficient catalytic racemization of secondary alcohols.,TETRAHEDRON LETTERS,39,0000005545(1998)

Infrared and Raman spectroscopy of 9,9 '-spirobifluorene, bis(2,2 '-biphenylene)silane, and bis(2,2 '-biphenylene)germane. Vibrational assignment by depolarization measurement and HF and density functional theory studies,JOURNAL OF PHYSICAL CHEMISTRY A,102,0000001139(1998)

Chiral 2,2-disubstituted cyclopropanecarboxylic acids: Effective derivatizing agents for analysis of enantiomeric purity of alcohols and for resolution of 1,1'-bi-2-naphthol,TETRAHEDRON LETTERS,38,0000003959(1997)

N-protonation vs O-protonation in strained amides: Ab initio study,JOURNAL OF ORGANIC CHEMISTRY,62,0000004068(1997)

Pd-Catalyzed asymmetric allylic alkylations using various diphenylphosphino(oxazolinyl)ferrocene ligands,TETRAHEDRON-ASYMMETRY,8,0000001179(1997)

"Effects of solvent and lithiating agent on stereoselectivity in lithiation of chiral 1,1'-bis(oxazolinyl)ferrocenes",TETRAHEDRON LETTERS,37,0000006137(1996)

An efficient diastereoselective synthesis of chiral oxazolinylferrocene compounds,JOURNAL OF ORGANIC CHEMISTRY,61,0000004937(1996)

국내전문학술지
철 알킨일(에톡시)카르벤 착물 유도체와 아민의 반응,대한화학회지,40,571~578(1996)