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ۼ : 15-05-06 09:33
[15.04] -N-Heterocyclic Carbene Nitric Oxide Radicals
 ۾ :
ȸ : 1,514  

 

N-Heterocyclic Carbene Nitric Oxide Radicals

Junbeom Park, Hayoung Song, Youngsuk Kim, Bit Eun, Yonghwi Kim, Dae Young Bae, Sungho Park, Young Min Rhee, Won Jong Kim, Kimoon Kim, and Eunsung Lee

N-Heterocyclic carbene-stabilized nitric oxide radicals were prepared by direct addition of nitric oxide to two N-heterocyclic carbenes in solution phase. The compounds were fully characterized by X-ray crystallography and EPR. The nitric oxide moiety in the solid compounds obtained can be thermally transferred to another N-heterocyclic carbene, suggesting potential applications to NO delivery.

ϻȭҴ ¿ ϴ Į̴. ϻȭҴ Ȯ, ȣ  ϴ , ϻȭ ü ȹ θ ǰ ִ. ַ ̱ݼ ȭչ ϻȭҿ ϴ ˷ ִ. , ⹰ ̿ ϻȭ ȹ ˷ ʴ. ϻȭҿ ϱ , Į ״ ϴ ȭչ ߰ߵ ʾҴ. N-׷ΰ ī ⹰ν پ Į ȭչ Ͽ Į ȭŲٰ ˷ Դ. ڵ ؼ, Ǹ, ϴ پ Į ȭչ N-׷ΰ ī ȭϴµ Ͽ. N-׷ΰ ī ̿ ü ϻȭ Į ü Į ȭϴ Ͽ, ߵ ڼ б (Electron Paramagnetic Resonance Spectroscopy, EPR) X м (X-ray crystallography) ԸǾ. ߵ ϻȭ Į ϻȭ ظ ϴ. ̴ ϻȭ ɼ ְ, Ǿ, о߷ ɼ Ѵ. ȭȸ J. Am. Chem. Soc. 4 15 Ǿ.


 
 

Total 73
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