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ۼ : 14-01-08 09:45
[13.12] ⹮ - Cucurbit[7]uril: A High-Affinity Host for Encapsulation of Amino Saccharides and Supramolecular Stabilization of Their -Anomers in Wate
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Cucurbit[7]uril: A High-Affinity Host for Encapsulation of Amino Saccharides and Supramolecular Stabilization of Their a-Anomers in Water

Y. Jang, R. Natarajan, Y. H. Ko, and K. Kim*

Sweet pockets: Cucurbit[7]uril binds protonated amino saccharides with excellent affinity in water. It stabilizes the a-anomers of the bound saccharides, thereby preventing any mutarotation in water, which is otherwise impossible.

ΰ ü ๰ о߷ ϸ, ׻󿡼 ۿϴ ΰ ü(artificial saccharide receptor) ȭ Ǵ ʺ ȭко߿ ſ ̷ο ̴. ĿƮ[7](CB[7]) ׻󿡼 ϰ ƹ̳ ߰Ͽ. CB[7] ƹ̳ ̷ ְ շ Ka = 1.6 x 104 M-1 Ͽ (D-). CB[7] ƹ̳ ȸ Ƴ ȭ ԸϿ. ƹ̳ CB[7] շ, ۶ĭ(glycan)м ΰ ƾ Ȥ ȣۿ Ž (lipid)-CB[7] ü , ƹ̳۷ڽõ ü ๰ ۰ ϸ Ѵ. ̷ ȭ ȰԹɹ(Angewante Chemie) Ǿ.

 


 
 

Total 78
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36 [13.12] ⹮ - Cucurbit[7]uril: A High-Affinity Host for Encapsulation of Amino Saccharides and Supramolecular Stabilization of Their -Anomers in Wate 01-08 1707
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